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I think she did this because as a girl, she knows more about Cho than Harry probably does and maybe knew what type of girl she was and that she wouldn't be good for him. That can be seen as love, but I see that as trying to look out for a friend by monitering her around him.
Come now, we all know just how observent Hermione is, she notices every single detail, right down to Umbrige's subtext (and who honestly listens to teachers speeches?).